(Nitrato-κO)tris[tris(4-fluorophenyl)phosphane-κP]copper(I)
نویسندگان
چکیده
منابع مشابه
Poly[[μ2-1,2-bis(diphenylphosphanyl)-1,2-diethylhydrazine]-μ4-nitrato-μ2-nitrato-silver(I)]
The title compound, [Ag(2)(NO(3))(2)(C(28)H(30)N(2)P(2))](n), crystallizes in polymeric α-helices. Three O atoms from three different nitrate ions in equatorial positions and two Ag atoms at axial positions set up a trigonal bipyramid. These units are linked by the phosphine ligands into endless helical chains that run along the c axis. The crystal used for the data collection was a racemic twin.
متن کاملBis(2-aminopyrimidine-κN 1)aqua(nitrato-κO)(nitrato-κ2 O,O′)zinc(II)
The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-amino-pyrimidine, [Zn(NO(3))(2)(C(4)H(5)N(3))(2)(H(2)O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry about the Zn(II) atom is a distorted octa-hedron. Intra-molecular N-H⋯O hydrogen bonds occu...
متن کاملAqua(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)(nitrato-κO)(nitrato-κ2 O,O′)zinc
In the title compound, [Zn(NO(3))(2)(C(12)H(12)N(2))(H(2)O)], the Zn(II) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a chelating 4,4'-dimethyl-2,2'-bipyridine ligand, one water O atom, one O atom from a monodentate nitrate anion and two O atoms from a chelating nitrate anion. In the crystal, there are aromatic π-π contacts between the pyridine rings [centroid...
متن کاملcatena-Poly[[(nitrato-κO)(1,10-phenanthroline-κ2 N,N′)manganese(II)]-μ-nitrato-κ2 O:O′]
In the crystal structure of the title compound, [Mn(NO(3))(2)(C(12)H(8)N(2))](n), the Mn(II) atoms are linked by nitrate ligands to form a chain. Each Mn(II) atom is five-coordinated by two N atoms of a 1,10-phenanthroline ligand and three O atoms of two nitrates within a trigonal-bipyramidal coordination geometry. In the crystal structure, the chains are linked by hydrogen bonds into a polymer...
متن کاملTetrakis(1H-benzimidazole-κN 3)(nitrato-κO)copper(II) nitrate
In the title salt, [Cu(NO(3))(C(7)H(6)N(2))(4)]NO(3), one nitrate anion is coordinated to the Cu(II) atom, which is also coordinated by the N atoms of four N-heterocycles. The geometry at the metal atom is a square pyramid in which the O atom of the anion occupies the apical position [Cu-O = 2.468 (5) and 2.590 (7) Å in the two independent formula units]. The cation lies on a twofold rotation a...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812043346